We can use multiple web browsers to separate accounts. But if we want to use only one such as Firefox. This method can be a solution:
Personal-account set
- iGoogle: by this time it's not available to company account yet.
- Gmail Notifier
- Google Talk
Gmail Notifier and Google Talk call Gmail at different places despite of same "www.google.com/...", no matter company has set alias to another URL or not. And then from Gmail, each session links to within its own place for other services (Calendar, Docs, Sites).